High temperatures and dry conditions play a significant role in the formation of hydrophobic soils, which are characterized by their water-repelling properties due to the presence of organic compounds on soil particles. These environmental factors contribute to the development and intensification of soil hydrophobicity through distinct but interconnected mechanisms.
High Temperatures and Fire-Induced Effects
High temperatures, particularly those associated with wildfires or intense heating, can significantly enhance soil hydrophobicity. When soils are exposed to temperatures between 175 and 260 °C, often during the combustion of surface fuels or forest floor material, hydrophobic organic substances are volatilized. These substances then move downward through the soil profile and condense on cooler underlying layers, forming a water-repellent layer. Research indicates that temperatures above 250 °C can re-volatilize these substances, potentially broadening the depth of the hydrophobic layer15. However, if temperatures exceed 290 °C, the hydrophobic compounds may be destroyed, reducing repellency at the surface but potentially causing condensation at deeper, cooler layers5.
The temperature gradient in the soil is critical, as dry soil is a poor conductor of heat, leading to rapid temperature decreases with depth. For instance, at a depth of 50 mm, temperatures are unlikely to exceed 150 °C unless prolonged heating occurs, such as during smoldering fires5. Laboratory studies simulating wildfire conditions have shown that in dry soils, water repellency is often most pronounced at shallow depths (less than 20 mm) after heating, while in wetter soils, repellency can occur deeper (20 to 50 mm) due to slower heat transfer and condensation of hydrophobic substances at lower temperatures5.
Dry Conditions and Natural Repellency
Dry conditions, even in the absence of fire, contribute to the development of hydrophobic soils. Prolonged drought or low soil moisture reduces microbial activity, which normally breaks down waxy, organic residues from plant material or fungal activity. As a result, these hydrophobic substances accumulate and coat soil particles, particularly in sandy soils with smaller surface areas3. Studies have observed that unheated, very dry soils often exhibit natural repellency, especially at shallow depths, due to the pre-existing presence of these organic coatings5.
Dry conditions also influence the behavior of polar compounds in the soil. When soil moisture is low, the shape of these compounds can change, exposing their hydrophobic ends and creating a water-repellent surface on soil particles. This effect is exacerbated in dry soils because the lack of water limits the exposure of hydrophilic ends that would otherwise allow water infiltration3.
Combined Impact of Heat and Dryness
The interaction between high temperatures and dry conditions often amplifies soil hydrophobicity. Dry soils heat more quickly at the surface compared to wet soils, but heat transfer to deeper layers is slower, concentrating hydrophobic effects near the surface5. Post-fire or post-drought scenarios can lead to severe water repellency, reducing the soil's ability to absorb water when rain finally occurs. This can result in increased runoff and erosion, as well as challenges for plant growth by limiting water and nutrient availability23.
In summary, high temperatures from fires volatilize and redistribute hydrophobic substances within the soil profile, while dry conditions facilitate the accumulation of these substances by hindering microbial decomposition and altering molecular interactions. Together, these factors create and sustain hydrophobic soils, particularly in fire-prone or drought-affected regions135.
- https://www.sciencedirect.com/science/article/abs/pii/S0016706110001953
- https://www.linkedin.com/pulse/science-behind-hydrophobic-soils-cwisesoilcarbonsolutions
- https://floodriskamerica.com/blog/why-floods-follow-periods-of-drought/
- https://ucanr.edu/sites/default/files/2010-06/17252.pdf
- https://forest.moscowfsl.wsu.edu/engr/library/Robichaud/Robichaud2000f/2000f.pdf
- https://bsssjournals.onlinelibrary.wiley.com/doi/full/10.1111/ejss.13102
- https://www.sciencedirect.com/science/article/abs/pii/S0167198723002222
- https://www.theseedcollection.com.au/blog/hydrophobic-soil-treatment-and-prevention

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